Reactividad de los compuestos organometálicos en disolventes no convencionales (fluidos supercríticos, líquidos iónicos, etc.)


Reactivity of organometallic complexes in non conventional solvents (supercritical fluids, ionic liquids, …)


Referencias seleccionadas:

Selected references:

- New insights into the mechanism of oxodiperoxomolybdenum catalysed olefin epoxidation and the crystal structures of several oxo peroxo molybdenum complexes.

Dalton Trans. 2012, 41, 6942.

- Influence of N donor bases and the solvent in oxodiperoxomolybdenum catalysed olefin epoxidation with hydrogen peroxide in ionic liquids.

Dalton Trans. 2011, 40, 5210.

- Olefin epoxidation in solventless conditions and apolar media catalysed by specialised oxodiperoxomolybdenum complexes.

J. Mol. Catal. A 2011, 338, 111.

- Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species.

Chem. Commun. 2010, 46, 5933.

- Supercritical carbon dioxide, a new medium for aerobic alcohol oxidations catalysed by copper-TEMPO.

Dalton Trans. 2010, 39, 900.

- Methyltrioxorhenium Complexes of Polydimethylsiloxane Functionalised Pyridine as Efficient Olefin Epoxidation Catalysts in Solventless and Low Polar Solvent Conditions.

Organometallics 2009, 28, 2855.

- Carbosilane dendrons as solubilizers of metal complexes in supercritical carbon dioxide.

Organometallics 2006, 25, 4138.