Estabilización de moléculas insaturadas por coordinación a complejos del grupo 6 en bajo estado de oxidación.
Stabilization of unsaturated molecules by coordination to Group 6 complexes in low oxidation state.
Referencias seleccionadas:
Selected references:
- DFT Analysis of Bis-ethylene Complexes of Molybdenum and Tungsten: Substitution Reactions and Bond Dissociation Energies.
Organometallics 2003, 22, 3117.
- Theoretical analysis of bis(ethylene) complexes of molybdenum and tungsten
J. Organomet. Chem. 2002, 663, 83.
- Synthesis and Reactivity of Bis(ethylene)-Phosphite Complexes of Molybdenum(0).
Inorg. Chim. Acta 1998, 272, 125.
- Reactivity of bis(ethylene) complexes of molybdenum(0) versus a,b unsaturated carbonyl compounds. Crystal and molecular structure of Mo(H2C=CH-COOMe)3(PMe3).
J. Organomet. Chem. 1998, 566, 211.
- Synthesis, Molecular structure and MO considerations on Mo(PhCCCOOEt)3(PMe3).
J. Organomet. Chem. 1998, 569, 21.
- Bis(ethylene) complexes of molybdenum and tungsten(0) containing the CH3(CH2PMe2)3 ligand: synthesis, solution conformation and reactivity.
J. Chem. Soc., Dalton Trans. 1997, 3749.